Important factors to consider when developing physical verification decks:
1 Make sure correct and complete metal connectivity is established.
2 Make sure all key layers and device structures are used in device LVS extraction.
3 All soft connects (connection by diffusion)  need to handle correct to flag unintentional circuit shorts or leakages. 
4 Make sure all PN junction and breakdown effect are implemented in CDK and verified in PV.
5 Make sure guardring and iso-p-tank are extracted correctly especially for complex layout style.
6 Ensure to verify post extraction parasitic capacitance and resistor values are correct and align to the process. 
7 Double check to make sure no double counting of junction capacitance.  
8 Make sure all supported device layout styles are supported by both DRC and LVS.
9 Take advantage of version control, automatic script and MACRO when developing DRC and LVS/RCX decks.
10 Make sure PV decks takes care of both drawn and generated layers.
11 Make sure DRC deck is checking all generic rules first, then exact rule, then device specific rules. This can enhance DRC coverage.
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